I said I had used one in place of the other before, but truthfully it was only because I wasn’t paying attention to my recipe and didn’t realize what I had done until after everything was already mixed. Oops. But after some quick research, I discovered that they are interchangeable in a pinch. The website Joy of Baking states the two products are both “chemical leavening agents that cause batters to rise when baked.” They suggest an appropriate substitution is two teaspoons of a double-acting baking powder. It is also noted that too much baking powder can give batter a bitter taste, so that’s why it’s really appropriate only in a pinch. If you’re interested in looking at more of the chemical reaction of baking soda, here’s a link.
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